苯酐催化剂表面纹理的表征及表面纹理模型的探讨

高等学校化学学报 ›› 1992, Vol. 13 ›› Issue (10): 1313.

苯酐催化剂表面纹理的表征及表面纹理模型的探讨

段世铎, 阳葵

天津大学化学系, 天津, 300072

收稿日期:1992-01-20 修回日期:1992-04-02 出版日期:1992-10-24 发布日期:1992-10-24
通讯作者: 段世铎
基金资助:
国家自然科学基金

Characterization of the Surface Texture of Catalysts for Naphthalene Oxidation to Phthalic Anhydride(PA) and Exploration of Surface Texture Model

DUAN Shi-Duo, YANG Kui

Department of Chemistry, Tianjin University, Tianjin, 300072

Received:1992-01-20 Revised:1992-04-02 Online:1992-10-24 Published:1992-10-24

摘要/Abstract

关键词: 催化剂纹理, 表面纹理模型, 苯酐催化剂

Abstract: The catalyst texture is one of the important features for characterizing catalyst properties.In this paper,the Image Texture Analysis Technique is introduced to analyze the SEM images of PAcatalysts in order to obtain the catalyst texture information.It is found that the texture entropy feature(F9) is in close relation with the activity of catalysts.An appropriate surface texture model corresponding to the high activity catalysts for the oxidation of naphthalene to PA is deduced as: The model is consistent with the results of activity evaluation andphysical chemistry analysis such as XRD,TPD-MS,ESR.

Key words: Catalyst texture, Surface texture model, Catalysts for naphthaiene oxidation to phthalic anhydride

TrendMD:

段世铎, 阳葵. 苯酐催化剂表面纹理的表征及表面纹理模型的探讨. 高等学校化学学报, 1992, 13(10): 1313.

DUAN Shi-Duo, YANG Kui. Characterization of the Surface Texture of Catalysts for Naphthalene Oxidation to Phthalic Anhydride(PA) and Exploration of Surface Texture Model. Chem. J. Chinese Universities, 1992, 13(10): 1313.