高等学校化学学报

高等学校化学学报 ›› 1991, Vol. 12 ›› Issue (10): 1378.

• 论文 • 上一篇    下一篇

两种结构钼磷酸的催化氧化行为

吴通好, 李建庆, 王国甲, 杨洪茂, 张恒彬, 魏诠, 姜玉子   

  1. 吉林大学化学系, 长春, 130023
  • 收稿日期:1990-06-26 出版日期:1991-10-24 发布日期:1991-10-24
  • 通讯作者: 吴通好
  • 基金资助:

    国家自然科学基金

Catalytic Oxidation Properties of Dawson and Keggin Structure Molybdophosphoric Acids

Wu Tong-hao, La Jian-qing, Wang Guo-jia, Yang Hong-mao, Zhang Heng-bin, Wei Quan, Jiang Yu-zi   

  1. Department of Chemistry, Jilin University, Changchun, 130023
  • Received:1990-06-26 Online:1991-10-24 Published:1991-10-24

PDF (PC)

被引次数

44

摘要： 考察了Dawson与Keggin结构钼磷酸的催化氧化行为,并与结构特性进行了关联,结果发现,Dawson结构的杂多酸对氧化脱氢及插入氧反应均有更高的活性。

关键词: Dawson结构钼磷酸, Keggin结构钼磷酸, 异丁醛氧化

Abstract: In the present work, we examined the catalytic oxidation activities of Dawson and Keggin structure molybdophosphoric acids and related the results with the structureal characteristics. The results show that Dawson structure heteropoly acids have higher activities to either oxidative dehydrogenation reaction or oxygen addition reaction.

Key words: Dawson structure molybdophosphoric acid, Keggin structure molybdophosphoric acid, Oxidation of isobutylaldehyde

TrendMD: