高等学校化学学报

高等学校化学学报 ›› 1989, Vol. 10 ›› Issue (5): 522.

• 研究简报 • 上一篇    下一篇

双(正-辛基亚砜)乙烷钴的配合物

张若桦, 张求稳, 张子静   

  1. 南开大学化学系
  • 收稿日期:1987-08-28 出版日期:1989-05-24 发布日期:1989-05-24
  • 通讯作者: 张若桦

The Cobalt(Ⅱ) Complexes of Bis(n-octylsulfinyl)-ethane

Zhang Ruohua, Zhang Qiuwen. Zhang Zijing   

  1. Department of Chemistry, Nankai University, Tianjin
  • Received:1987-08-28 Online:1989-05-24 Published:1989-05-24

PDF (PC)

摘要： 低碳链的双亚砜过渡金属配合物己经合成[1.2],而高碳链的双亚砜与半径较小的第一过渡系配合物还未见报道。为继续对这一类配合物进行研究,我们合成了4个双(正-辛基亚砜)乙烷钴的配合物,并对它们的性质进行了研究。

关键词: 双(正-辛基亚砜)乙烷, 钴配合物

Abstract: Four cobalt( Ⅱ ) complexes of bis(n-octylsulfinyl)ethane have been perpared. These complexes have been characterized by elemental analysis, molar conductance, visible near-infrared, infrared spectra and molar susceptibility. They have the following formula [Co(α-BOSE)3](ClO4)2, [Co2(β-BOSE)5(ClO4)2](ClO4)<2·4H2O,[Co(α-BOSE)2(NO3)2],[Co(β-BOSE)(NO3)·H2O]NO3.The ligand field parameters of complexes and other data are also shown.

Key words: Bis(n-octylsulfinyl)ethane, Cobalt(Ⅱ ) complex

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