高等学校化学学报 ›› 1989, Vol. 10 ›› Issue (4): 406.

• 研究论文 • 上一篇    下一篇

关于Aai-Bbj型缩聚物网络结构的研究(Ⅰ)--溶胶凝胶分配理论

郑福安, 胡钰新, 闵永刚, 汤心颐   

  1. 吉林大学化学系
  • 收稿日期:1987-09-24 出版日期:1989-04-24 发布日期:1989-04-24
  • 通讯作者: 郑福安

The Investigation of Network Structure of Aai-BbjType Polycondensate( Ⅰ)--The Sol-Gel Distribution Theory

Zheng Fuan, Hu Yuxin, Min Yonggang, Tang Xinyi   

  1. Department of Chemistry, Jilin University, Changchun
  • Received:1987-09-24 Online:1989-04-24 Published:1989-04-24

摘要: 本文考虑了分子内环化反应对溶胶凝胶分配的影响,用新的方法推导了包含各种反应参数的理论方程。以聚酯为模型化合物的实验结果支持本文所得到的理论结果。

关键词: 网络结构, 溶胶凝胶分配, 分子内环化, Aaj-Bbj型缩聚物

Abstract: This paper reports the effect of intramolecular cyclization reaction and proposes a new theoretical model and method, evaluates the modified sol-gel distribution theory including all parameters of reaction. Using polyesters as a model compound to test the theory, we found the theoretical values agreed with the c perimental ones.

Key words: Network structure, Sol-gel distribution, Intramolecular cyclization, Aai-Bbjtype polycondensate

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