高等学校化学学报 ›› 1988, Vol. 9 ›› Issue (9): 891.

• 论文 • 上一篇    下一篇

三角波交流示波极谱的研究(Ⅲ)——双组分三角波交流示波极谱理论

祁洪, 马新生, 高鸿   

  1. 南京大学化学系
  • 收稿日期:1987-03-16 出版日期:1988-09-24 发布日期:1988-09-24
  • 通讯作者: 祁洪

Investigation on Triangular-wave AC Oscillopolarography(Ⅲ)——Theory of Two Components

Qi Hong, Ma Xinsheng, Gao Hong(H. Kao)   

  1. Department of Chemistry, Nanjing University, Nanjing
  • Received:1987-03-16 Online:1988-09-24 Published:1988-09-24

摘要: 本文逐步运用初始条件,建立了双组分三角波交流示波极谱理论。该理论可较好地还原到前文报道的单组分状态时的各类方程,与实验结果一致。讨论了影响去极剂切口性质的主要因素,如去极剂浓度,前还原组分浓度以及三角波电流直流分量和电流扫描速率。

关键词: 交流示波极谱, 三角波电流扫描, 双组分

Abstract: Theory of triangular-wave oscillopolarograms in the solution containing two depolarizer has been derived from the stepwise application of initial conditions' The result can be returned to what obtained by one depolarizer, which makes an agreement with expeiment. Factors affecting the incision are discussed.

Key words: AC oscillopolarography, Triangular-wave current sweeping, Theory of two components

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