高等学校化学学报 ›› 1988, Vol. 9 ›› Issue (8): 764.

• 论文 • 上一篇    下一篇

[Mn(H2O)4(NCS)2)(18C6)和(Co(H2O)4(NCS)2)(18C6)单晶的培养及物性表征

杜高英1, 张文兴2, 樊悦朋2   

  1. 1. 山东省分析测试中心;
    2. 山东大学化学系
  • 收稿日期:1987-01-12 出版日期:1988-08-24 发布日期:1988-08-24
  • 通讯作者: 樊悦朋

The Crystal Crowth and Their Properties of cMn(H2O)4(NCS)2](18C6) and cCo(H2O)4(NCS)2](18C6)

Du Gaoying1, Zhang Wenxing2, Fan Yuepeng2   

  1. 1. Analytical and Test Confer of Shandong Province, Jinan;
    2. Department of Chemistry, Shandong University, Jinan
  • Received:1987-01-12 Online:1988-08-24 Published:1988-08-24

摘要: 用凝胶法和蒸发法分别培养出配合物[Mn(H2O)4(NCS)2]18C6)和[Co(H2O)4(NCS)2](18C6)的单晶。对两个配合物进行了溶解性能的测试、元素分析、电导测量、红外光谱分析、热分析和质谱分析。表征的指派为晶体结构分析结果所证实。

关键词: 冠醚配合物, 单晶的培养, 冠醚性质

Abstract: The crystal growth of CMn(H2O)4(NCS)2](18C6) and [Co(H2O)4-(NCS)2](18C6) were separated by gel diffusion method and solvent evaporation method.The pink slice like crystal and rose red lump like crystal were obtaimed. The elememtal analyses of complex crystals was done.The properties of solubility, electroconductivity measurement, IR, DTA-TG-DTGanalyses. and MSwere respectively tested. All results above and their designation were confirmed by X-ray single crystal structure analysis.

Key words: Crown complexes, Single crystal goovvth, Crown properties

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