高等学校化学学报

高等学校化学学报 ›› 1988, Vol. 9 ›› Issue (3): 295.

• 研究简报 • 上一篇    下一篇

1-氨基环己基苯基膦酸酯和1-环丙基膦酸酯的合成

陈茹玉, 刘增勋, 陈林志   

  1. 南开大学元素有机化学研究所
  • 收稿日期:1986-10-10 出版日期:1988-03-24 发布日期:1988-03-24
  • 基金资助:

    国家自然科学基金

The Synthesis of 1-Aminocyclohexyl Phenyl Phosphonates and 1-Cyclopropyl Phosphonates

Chen Ruyu, Liu Zengxun, Chen Linzhi   

  1. The Institute of Elemento-Organic Chemistry, Nankai University, Tianjin
  • Received:1986-10-10 Online:1988-03-24 Published:1988-03-24

PDF (PC)

摘要： 1-氨基环烷基膦酸酯类化合物是一种新型高效植物生长调节剂[1],与某些化合物混合使用[2],不但可以作脱水、脱叶剂还可以用作除草剂,抑制杂草生长,为了进一步探索这类化合物的结构与活性关系,我们合成出4个新的1-氨基环己基取代苯基膦酸酯化合物,并讨论了反应机理.

Abstract: In this paper the synthesis of four new 1-amino cyclohexyl phenyl phospho-nic acids was reported.Two new intermediates "Pyrazoline" were prepared by the addition of diazomethane to the substituted olefins.After the elemination of nitrogen by heating, the substituted cyclopropyl phosphonates were obtained in good yields.

TrendMD: