高等学校化学学报 ›› 1988, Vol. 9 ›› Issue (3): 277.

• 研究简报 • 上一篇    下一篇

8-羟基喹啉合十钒酸盐的研究(Ⅲ)——锂、钾、铵盐的合成、鉴定与性质

杜尧国1, 王君1, 王孝霞1, 修振崑1, 杜文才2   

  1. 1. 吉林大学环境科学系;
    2. 辽宁师范大学化学系
  • 收稿日期:1986-09-02 出版日期:1988-03-24 发布日期:1988-03-24

An Investigation on the Metal Decavanadates Coordinating with Oxine (Ⅲ)——The Synthesis, Characterization and Properties of Lithium, Potassium and Ammonium Salts

Du yaoguo1, Wang Jun1, Wang Xiaoxia1, Xiu Zhenkun1, Du Wencai2   

  1. 1. Department of Environmenial Science Jilin University, Changchun;
    2. Department of Liaoning Nornal University, Dalian
  • Received:1986-09-02 Online:1988-03-24 Published:1988-03-24

摘要: 在合成与研究钠盐的基础上[1,2],我们又合成了锂、钾和铵盐,通过元素分析、分子量测定、质谱分析、X射线衍射、紫外和红外吸收光谱分析和热重分析确定了新化合物的组成与化学式并推测了化合物的结构式。

Abstract: The decayahadates of Li+,K+,NH4+ coordinating with oxine were prepared.By means of elementary analysis, molecular weight determination, GC/MS, X-rays diffraction, UVand IRspectrophotographies and thermo-analysis, the authors suggested that the structural formulae of Li+,K+,NH4+ salts are as follows:[Li(HOx)]2[Li(HOx)3]4(H2V10O28(Ox)2]·4HOx,[K(HOx)]4[K(HOx)2]2[H6V10O28(Ox)6]·2HOx,and [NH4(HOx)]4[NH4(HOx)2]2[H4V10O28(Ox)4.

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