高等学校化学学报 ›› 1988, Vol. 9 ›› Issue (2): 113.

• 论文 • 上一篇    下一篇

稀土苦味酸配合物的合成及其结构研究

田永驰1, 梁映秋1, 倪嘉缵2   

  1. 1. 吉林大学理论化学研究所;
    2. 中国科学院长春应用化学研究所
  • 收稿日期:1986-09-11 出版日期:1988-02-24 发布日期:1988-02-24

Syntheses and Structures of Rare Earth Picrate Hydrates

Tian Yongchi1, Liang Yingqiu1, Ni Jiazan2   

  1. 1. Institute of Theoretical Chemistry, Jilin University, Changchun;
    2. Changchun Institute of Applied Chemistry, Academia Sinica, Changchun
  • Received:1986-09-11 Online:1988-02-24 Published:1988-02-24

摘要: 合成了15种稀土苦味酸配合物,进行了元素分析,并测定了振动光谱、XPS谱和X射线单晶衍射的晶胞参数,对配位情况和金属-氧键的性质进行了计论。

Abstract: Fifteen rare earth picrate hydrates have been synthesized in the reaction of RE2O3 with picric acid. Some results of elemental analysis, vibrational spectra, XPS, thermal analysis and lattic parameters are reported, and molecular structures and properties have been discussed.

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