高等学校化学学报

高等学校化学学报 ›› 1988, Vol. 9 ›› Issue (12): 1268.

• 论文 • 上一篇    下一篇

界面缩聚法合成双(烯基环戊二烯基)钛(锆)聚醚的研究

沈宏康, 魏荣宝, 梁娅, 林琳, 薛其峰, 陈晓津, 孟昭全   

  1. 天津理工学院化工系
  • 收稿日期:1987-04-07 出版日期:1988-12-24 发布日期:1988-12-24
  • 通讯作者: 魏荣宝

Synthesis of Bis(Alkenylcyclopentadienyl) Titanium(Zir-conram)Polyethers by Interfacial Polycondensation

Shen Hongkang, Wei Rongbao, Liang Ya, Lin Lin, Xue Qifeng, Chen Xiaojin, Meng Zhaoquan   

  1. Department of Chemical Technology, Tianjin Institute of Technology, Tianjin
  • Received:1987-04-07 Online:1988-12-24 Published:1988-12-24

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被引次数

1

摘要： 本文通过界面缩聚法利用双(烯基环戊二烯基)钛(锆)二氯化物与二酚反应,制成了16个新的高分子化合物,对它们进行了IR、TGA和分子量的测定。文中还对反应条件与分子量的关系进行了讨论。

关键词: 界面缩聚, 双(烯基环戊二烯基)钛(锆)二氯化物, 双(烯基环戊二烯基)钛(锆)聚醚

Abstract: Bis (Alkenylcyclopentadienyl)Titanium(Zirconium) dichlorides werereacted with diphenols through interfacial polycondensation to give a series of16 new polymers. IK, TG/DTG, solubility and mol. wt. determinations weremade. The relationships between experimental parameters and,molecular weight werediscussed.

Key words: Interfacial polycondesation, Bis (Alkenylcyclopentadienyl) titanium (Zirconium) dichlorides, Bis(Alkenylcyclopentadienyl)titanium (zirconium) poly-ether

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