高等学校化学学报 ›› 1988, Vol. 9 ›› Issue (1): 91.

• 研究简报 • 上一篇    下一篇

二氧化碳在Pd/SiO2和La-Pd/SiO2上的催化氢化反应

姜玄珍, 鲍坚斌, 周涛, 陈旸   

  1. 浙江大学化学系
  • 收稿日期:1986-08-15 出版日期:1988-01-24 发布日期:1988-01-24
  • 基金资助:

    国家自然科学基金

Catalytic Hydrogenation of CO2 over Pd/SiO2 and La-Pd/SiO2 Catalysts

Jiang Xuanzhen, Bao Jianbin, Zhou Tao, Chen Yang   

  1. Department of Chemistry, University of Zhejiang, Hangzhou
  • Received:1986-08-15 Online:1988-01-24 Published:1988-01-24

摘要: 对CO2在附载型Pd催化剂上的氢化反应的研究迄今报道不多[1,2],且都在加压条件下进行,对常压下助催剂如何改善Pd的催化行为未见报道。本文探讨了Pd/SiO2催化剂,未加与掺加助催剂La(NO3)3后,其Pd粒大小、CO2的吸附性能及CO2/H2催化活性等方面都有显著差异。

Abstract: The catalytic hydrogenalion of CO2 over lanthana promoted and unpromoted Pd/SiO2 was studied. The marked differences can be observed in catalytic activities of formation of methane and methanol.The turnover frequency of production of methane arid methanol are higher on lanthana promoted catalyst than that on unpro-moted one. These differences may be attributed to lanthana promotion effect by which the palladium particles may redispersed on the surface, meanwhile the function of the promoter probably create a number of basic active sites to modify the catalytic behavior of supported palladium catalysts on CO2 hydrogenationreactions.

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