多环聚梯型共轭烃及其稳定性

高等学校化学学报 ›› 1988, Vol. 9 ›› Issue (1): 52.

多环聚梯型共轭烃及其稳定性

李前树¹, 沈良骏², 张星辰³

1. 吉林大学理论化学研究所;
2. 安微师范大学化学系;
3. 石家庄师范专科学校

收稿日期:1986-08-27 出版日期:1988-01-24 发布日期:1988-01-24

Ladder-Like Polymers of Polycyclic Conjugated Hydrocarbon and its Stability

Li Qianshu¹, Shen Liangjun², Zhang Xingchen³

1. Institute of Theoretical Chemistry of JiLin University, ChangChun;
2. Department of Chemistry, Anhui Normal University, Wuhu;
3. Shijiazhuang Teachers Training School, Shijiazhuang

Received:1986-08-27 Online:1988-01-24 Published:1988-01-24

摘要/Abstract

摘要： 本文利用CNDO/2法讨论了一类新型共轭烃——多环聚梯型共轭烃存在的可能性。结果表明,对三元-五元环烃和四元-四元环烃为重复单元的直链多聚梯型共轭烃H₂-(-C₃C₅H₂-)-_nH₂和H₂-(-C₄HC₄H-)-_nH₂,在n是偶数时体系稳定。

Abstract: In this paper,according to the results of CNDO/2 quantum chemistry calculation, we have discussed the possibility on a set of novel conjugated shown that, hydrocarbons, ladder-like polymers of polycyclic conjugated hydrocabons. It is when n is a even number the molecules of chain ladder-like polymers of polycyclic conjugated hydrocabons with three menbered ring-five menbered ring or four menbered ring-four menbered ring as repeated unit, H₂-(-C₃C₅H₂) or H₂-(-C₄HC₄H-)-_nH₂, might be stable, which enables us to believe that the aformentioned molecules are possible potential synthesized objects.

TrendMD:

李前树, 沈良骏, 张星辰. 多环聚梯型共轭烃及其稳定性. 高等学校化学学报, 1988, 9(1): 52.

Li Qianshu, Shen Liangjun, Zhang Xingchen. Ladder-Like Polymers of Polycyclic Conjugated Hydrocarbon and its Stability. Chem. J. Chinese Universities, 1988, 9(1): 52.