高等学校化学学报

高等学校化学学报 ›› 1988, Vol. 9 ›› Issue (1): 36.

• 论文 • 上一篇    下一篇

超声波作用下芳基叔膦的断裂反应

许临晓, 陶凤岗, 于同隐   

  1. 复旦大学化学系
  • 收稿日期:1986-07-28 出版日期:1988-01-24 发布日期:1988-01-24

Fragmentation Reaction of Aryl Tertiary Phosphines Under Ultrasonic Irradiation

Xu Linxiao, Tao Fenggang, Yu Tongyin   

  1. Department of Chemistry, Fudan University, Shanghai
  • Received:1986-07-28 Online:1988-01-24 Published:1988-01-24

PDF (PC)

被引次数

9

摘要： 芳基叔膦和金属锂在超声波辐射下迅速反应产生芳基膦锂。文中对反应条件和起声波的作用进行了比较和讨论,并对该方法在合成芳基膦化合物中的应用进行了尝试。

Abstract: The fragmentation reaction of aryl tertiary phosphines in the presence of lithium can be promoted effectively by use of ultrasonic irradiation. The reactions under various conditions are compared and a discussion on the action of ultrasoundis also given hereof. Some organophosphine ligands have been prepared by use of this method.

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