酒石酸修饰电极及其铜的溶出伏安法研究

高等学校化学学报 ›› 1988, Vol. 9 ›› Issue (1): 31.

酒石酸修饰电极及其铜的溶出伏安法研究

方禹之, 李元生, 金利通

华东师范大学化学系

收稿日期:1986-07-14 出版日期:1988-01-24 发布日期:1988-01-24

Tartaric Acid Modified Electrode and Studies on Its Application for the Anodic Stripping Voltammetric Determination of Cu(Ⅱ)

Fang Yuzhi, Li Yuansheng, Jin Litong

Department of Chemistry, East China Normal University, Shanghai

Received:1986-07-14 Online:1988-01-24 Published:1988-01-24

摘要/Abstract

摘要： 本文研究了酒石酸修饰电极的制作,讨论了铜在酒石酸修饰电极上的反应机理,并确定了痕量铜的阳极溶出伏安法测定条件。

Abstract: We studied the preparation and performance of the tartaric acid modified electrodes, and found the conditions for determining trace copper (Ⅱ). These electrodes have good reproducibilily and the sensitivity is increased by one order of magnitude. There is a good linear relationship between peak height and concentration in the range of 1 to 20 ng/mLof Cu(Ⅱ). At the concentration of 10ng/mL of Cu(Ⅱ), the variation coefficient of six parallel determinations was 1.6%. Moreover, the reaction mechanism of Cu(Ⅱ) at the tartaric acid modified electrodes is discussed. The modified electrodes can increase the number of activated sites, and promote the exchange of electrons, so that both the enrichment efficiency and sensitivity are raised. The stripping process of copper at the modified electrodes is the same as that at glassy carbon electrodes.

TrendMD:

方禹之, 李元生, 金利通. 酒石酸修饰电极及其铜的溶出伏安法研究. 高等学校化学学报, 1988, 9(1): 31.

Fang Yuzhi, Li Yuansheng, Jin Litong . Tartaric Acid Modified Electrode and Studies on Its Application for the Anodic Stripping Voltammetric Determination of Cu(Ⅱ). Chem. J. Chinese Universities, 1988, 9(1): 31.