高等学校化学学报

高等学校化学学报 ›› 1987, Vol. 8 ›› Issue (9): 784.

• 研究简报 • 上一篇    下一篇

双钼配合物氧化还原特性的研究

孙文涛1, 张致贵2   

  1. 1. 长春冶金地质专科学校;
    2. 吉林大学化学系
  • 收稿日期:1986-02-28 出版日期:1987-09-24 发布日期:1987-09-24

A Study on the Oxidation-Reduction Characteristic of the Bimolybdenum Complex Compound

Sun Wentao1, Zhang Zhigui2   

  1. 1. Metallurgia Geologic Technical Colloge of Changchun, Changchun;
    2. Department of Chemistry, Jilin University, Changchun
  • Received:1986-02-28 Online:1987-09-24 Published:1987-09-24

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摘要： 以MoCl5和二乙胺基硫代甲酸钠为原料,在AlCl3存在下于甲醇溶液中反应,生成双钼配合物Mo[S2CN(C2H5)2]+[MoCl6]用循环伏安法研究了氧化还原特性。

Abstract: The cyclic voltammogram of bimolybdenum complex compound is reported. It is shown that there are a pair of redox peaks and one reduction peak in the cyclic voltammogram. The results indicate that the redox peak pair is corresponding to the redox reaction of Mo[S2CN(C2H5)2]4+, which is semireversible, but another reduction peak is corresponding to the reduction reaction of MoCl6-, which is irreversible.

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