高等学校化学学报 ›› 1987, Vol. 8 ›› Issue (7): 653.

• 论文 • 上一篇    下一篇

几种新型聚合物配体的合成及其固载化铑催化剂的醛化性能研究

孙君坦, 翁君凡, 李弘, 何炳林   

  1. 南开大学高分子化学研究所
  • 收稿日期:1985-11-12 出版日期:1987-07-24 发布日期:1987-07-24
  • 基金资助:

    国家教育委员会重点科学技术项目资助

Synthesis of Some New Polymeric Ligand-Anchored Rhodium Catalysts and Their Hydroformylation Properties

Sun Juntan, Weng Junfan, Li Hong, He Binglin   

  1. Institute of Polymer Chemistry, Nankai University, Tianjin
  • Received:1985-11-12 Online:1987-07-24 Published:1987-07-24

摘要: 本文使用交联聚苯乙烯为载体合成了几种新型的聚合物配体和固载化铑催化剂,考察了它们对二异丁烯和戊烯-1氢甲酰化反应的催化性能,探讨了催化剂的铑脱落现象。

Abstract: Several new types of polymeric ligand and the corresponding rhodium complexes, were synthesized using crosslinked polystyrene as the parent support. The catalytic properties of the catalvsts for the hydroformylation of diisobutylene and pentene-1 were investigated. The loss of rhodium of the catalysts was observed.

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