高等学校化学学报

高等学校化学学报 ›› 1987, Vol. 8 ›› Issue (7): 629.

• 论文 • 上一篇    下一篇

杂氮硅三环化合物(Ⅰ)和(Ⅱ)晶体结构的研究

林秀云1, 郑启泰1, 吴伸1, 张树德1, 沈福岭1, 王积涛2, 谢庆兰2, 廖仁安2, 李靖2   

  1. 1. 中国科学院生物物理研究所;
    2. 南开大学元素有机化学研究所
  • 收稿日期:1986-03-25 出版日期:1987-07-24 发布日期:1987-07-24
  • 基金资助:

    中国科学院科学基金

Study of the Crystal Structures of Silatranes (这里有图片198707-634-1.gif)

Lin Xiuyun. Zheng Qitai1, Wu Shen1, Zhang Shude1, Shen Fuling1, Wang Jitao1, Xie Qinglan2, Liao Renan2, Li Jing2   

  1. 1. Research Institute of biophysics, Academia Sinica, Beijing;
    2. Research Institute of Elemental-Organic Chemistry, Nankai University, Tianjin
  • Received:1986-03-25 Online:1987-07-24 Published:1987-07-24

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被引次数

4

摘要： 杂氮硅三环化合物Ⅰ和的分子结构用直接法解,经全矩阵最小二乘修正,得到它们的晶体学参数。并对它们的结构进行了比较和讨论。

Abstract: Silatrane Ibelongs to monoclinic system with space group P21/N(Z=4) and silatrane Ⅱ belongs to orthorhombic system with space group Pcab(Z= 8).The lattice parameters are.Ⅰ,α= 11.876(2)Å, 6=19.853(4)Å, c= 6.598(1)Å, β=110.12(2) Ⅱ.α= 19.653(4)Å, b=12.565(3)Å, c=12.570(3)Å.The structures were solved by RANTAN and refined by Full Matrix Least-Square Method. The final R-factors are 0.09 and 0.06, respectively.The N→Si bond of silatrane Iis shorter than that of Iand both of them are shorter than those of other kinds of silatranes.

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