高等学校化学学报

高等学校化学学报 ›› 1987, Vol. 8 ›› Issue (7): 623.

• 研究简报 • 上一篇    下一篇

二茂铁-四氰基乙烯络合体的光化学反应

孟继本1, 松浦辉男2   

  1. 1. 南开大学化学系;
    2. 日本京都大学工学部
  • 收稿日期:1985-12-25 出版日期:1987-07-24 发布日期:1987-07-24

Photochemical Reaction of Ferrocene-Tetracyanoethylene Complexes

Meng Jiben1, Matsuura T.2   

  1. 1. Department of Chemistry, Nanhai University, Tianjin;
    2. faculty of Endineering Kyoto University, Japan
  • Received:1985-12-25 Online:1987-07-24 Published:1987-07-24

PDF (PC)

被引次数

1

摘要： 在基态,由弱的电荷转移所形成的缔合体,一般称之为"电荷转移络合体",这种络合体的液相光化学反应,早已引起有机化学家的极大兴趣,并已进行了广泛的研究。

Abstract: Photochemical reaction of ferrocene-tetracyanoethylene (Fc-TCNE) complexes has been investigated. The photochemistry of (Fc-TCNE) in the solid-state is. distinct from that in solution. While only cyanoferrocene (F1) was obtained when the reaction was carried out in solution, both cyanoferrocene (F1) and 1,2-diferrocenyl-1,1,2,2-tetracyanoethane (F2) were obtained when it was carried out in the solid-state.

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