高等学校化学学报

高等学校化学学报 ›› 1987, Vol. 8 ›› Issue (6): 481.

• 论文 •    下一篇

La(ClO4)3-C11H12ON2-H2O三元体系相平衡及La(C11H12ON2)6(ClO4)3的合成

唐宗薰1, 陈运生1, 邹友忠2   

  1. 1. 西北大学化学系;
    2. 西北建筑工程学院
  • 收稿日期:1986-01-14 出版日期:1987-06-24 发布日期:1987-06-24
  • 基金资助:

    中国科学院科学基金

A Study on the Ternary System La(ClO4)3-C11H12ON2(Antipyrine)-H2O at 0℃ and the Preparation and Characteristics of the Hexaantipyrine Complex of Lanthanum Perchlorate La(C11H12ON2)6(ClO4)3

Tang Zongxun1, Chen Yunsheng1, Zou Youzhong2   

  1. 1. Northwestern University, Xi'an;
    2. Northwestern Architectural Engineering Gollege, Xi'an
  • Received:1986-01-14 Online:1987-06-24 Published:1987-06-24

PDF (PC)

摘要： 采用溶解度等温法研究了La(ClO4)3-C11H12ON2(安替吡啉)-H2O三元体系在0℃时的相平衡,并由此合成了La(C11H12ON2)6(ClO4)3配合物。还确定了该配合物的制备条件,测定了它的一些性质,并对其结构作了初步分析。

Abstract: The solubility of the ternary system La(ClO4)3-C11H12ON2(antipyrine)-H2O at 0 ℃ was studied. The hexaantipyrine complex of fhe lanthanum perch-lorate, La(C11H12ON2)6(C1O4)3, has been found in the system. The infrared spectrum, X-ray powder diffraction, solubility at 0 ℃ in water, melting point and density of the complex are recorded.

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