高等学校化学学报 ›› 1987, Vol. 8 ›› Issue (4): 372.

• 论文 • 上一篇    下一篇

氟代有机硅化合物的合成新方法

杜作栋, 陈剑华, 张承智   

  1. 山东大学化学系
  • 收稿日期:1985-10-29 出版日期:1987-04-24 发布日期:1987-04-24

New Synthesis of Fluorinated Organosilicon Compounds

Du Zuodong, Chen Jianhua, Zhang Chengzhi   

  1. Department of Chemistry, Shandong University, Jinan
  • Received:1985-10-29 Online:1987-04-24 Published:1987-04-24

摘要: 本工作利用CuCl/HOC2H4NH2催化剂,将1,2-二溴四氟乙烷与烯基有机硅化合物进行加威反应,制备了一系列新的含氟有机硅化合物,并进行了分析鉴定。对影响反应的诸因素做了初步探讨。

Abstract: CuCl/HOC2H4NH2catalystic system is used for catalysis of the addition of 1, 2-dibromotetrafluoroethane to organosilicon compounds containing vinyl group. Aseries of unreported organosilicon compounds containing fluorine have been synthesized. The structures of the compounds synthesized have been determinated by elemental analysis and spectroscopic methods (1HNMR and IR). Factors of affection on the reaction are investigated.

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