高等学校化学学报

高等学校化学学报 ›› 1987, Vol. 8 ›› Issue (3): 246.

• 研究简报 • 上一篇    下一篇

利用极性反转合成苄叉氯亚胺-1-α及苄叉氯亚胺的催化分解

张景榴   

  1. 福建师范大学化学系
  • 收稿日期:1985-10-31 出版日期:1987-03-24 发布日期:1987-03-24

Synthesis of Benzalchloroimine-1-d by Umpolung and Catalytic Decomposition of Benzalchloroimine

Zhang Jingliu   

  1. Department of Chemistry, Fujian Normal Universiiu, Fuzhou
  • Received:1985-10-31 Online:1987-03-24 Published:1987-03-24

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摘要： 文献报导二苯基N-无取代硫亚胺(Ⅰ)和醛作用可得对应的腈,曾设想其机理如下已知苄叉氯亚胺可分解成相应的腈,考虑到它在结构上与瞬时中间体B相似,如果在二苯硫醚共存下反应,可能形成结构上与B很相似的C。

Abstract: This paper reports a simple preparative method of benzalchloroimine-1-d. The kinetic study on the reaction of benzalchloroimine Ia-b with diphenyl sulfide in benzene has been carried out. From, p value of Hammett equation and the kinetic isotope effect, its mechanism of reaction was tendered.

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