高等学校化学学报

高等学校化学学报 ›› 1987, Vol. 8 ›› Issue (2): 187.

• 论文 • 上一篇    

2D-NMR研究中国生漆漆酚结构

黄照庚1, 邱峰1, 游江1, 钱保功1, 李丽云2, 裘鉴卿2, 袁汉珍2, 沈联芳2   

  1. 1. 武汉大学化学系;
    2. 中国科学院武汉物理研究所
  • 收稿日期:1985-09-26 出版日期:1987-02-24 发布日期:1987-02-24

2D-NMR Studies on the Structure of Urushiol of Chinese Lacquer

Huang Zhaogeng1, Qiu Feng1, You Jiang1, Qian Baogong1, Li Liyun2, Qiu Jianqing2, Yuan Hanzhen2, Shen Lianfang2   

  1. 1. Department of Chemistry, Wuhan University, Wuhan;
    2. Wuhan Institute, of Physics, Academia Sinica, Wuhan
  • Received:1985-09-26 Online:1987-02-24 Published:1987-02-24

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被引次数

31

摘要： 用离心旋转薄层层析法在涂渍AgNO3的硅胶板上成功地分离了乙酰化漆酚。对其主要组分(64.6%),用1H、13C常规谱,DEPT编辑谱,同核、异核化学位移相关二维谱,二维J谱,异核中继相干传递二维谱及弛豫时间T1等,确定了此化合物的结构与构型和1H、13C谱线归属。实验证明漆酚中此组分是3-十五碳烯烃(8′Z、11′E、13′Z)邻苯二酚,异核中继相干传递二维谱新技术能有效地应用于复杂未知化合物的结构测定。

Abstract: The urushiol diacetatcs have been successfully separated on the silica gel coated with silver nitrate by centrifugal rotation TLC. The structure and configuration of key component of urushiol (64.4%) were determined successfully by 1H and 13C conventional methods, DEPTtechnique, homo and beleronuclcar chemical shift correlation 2D-NMR, 2D-JNMR, helcronuclear relayed coherence transfer 2D-NMR, and relaxation time T1 investigation. The assignment of resonances for 1H and 13C were confirmed. Plenty of cvidence shows that the key component of urushiol is 3-(8'Z, 11'E, 13'Z-pentadccatrienyl) catechol. The results show that RELAY 2D-NMR new technique can be successfully applied to determining the structure of complicated unknown compounds.

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