高等学校化学学报 ›› 1987, Vol. 8 ›› Issue (2): 143.

• 研究简报 • 上一篇    下一篇

1,4,8,12-四甲基-1,4,8,12-四氮(杂)十五环烷合铜(Ⅱ)的合成

黄宁兴1, 夏敬谋2   

  1. 1. 暨南大学化学系;
    2. 中山大学化学系
  • 收稿日期:1985-09-14 出版日期:1987-02-24 发布日期:1987-02-24

The Synthesis of 1,4,8,12-Tetramethyl-1,4,8,12-Tetraazacyclopentadecane Copper(Ⅱ) Perchlorate

Huang Ningxing1, Xia Jinmou2   

  1. 1. Department of Chemistry, JiNan University, Guangzhou;
    2. Department of Chemistry, Zhongshan University, Guangzhou
  • Received:1985-09-14 Online:1987-02-24 Published:1987-02-24

摘要: 近二、三十年来,四氮(杂)大环配体配合物(A)一直是很活跃的研究领域。为了研究配体对过渡金属离子的环效应和过渡金属离子的氧化-还原特性,N原子的甲基取代物中12、14员环配体的合成已有报导。

Abstract: The synthesis of the new 15-membered macrocyclic, 1,4,8,12-tetramethyl-1, 4,8,12-tetraazacyclopentadecane and its coordination with copper (Ⅱ) are reported. The IR, UVand MS of the copper complex were measured.

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