高等学校化学学报

高等学校化学学报 ›› 1987, Vol. 8 ›› Issue (11): 963.

• 论文 • 上一篇    下一篇

2-苯基喹啉-4-甲酸稀土配合物的研究

崔建中, 曾正志, 邓汝温   

  1. 兰州大学化学系
  • 收稿日期:1986-07-08 出版日期:1987-11-24 发布日期:1987-11-24

Studies on the Complexes of Rare Earths with 2-Phenyl-Quinoline-4-Carboxylic Acid

Cui Jianzhong, Zeng Zhengzhi, Deng Ruwen   

  1. Ueparlment of Chemistry, Lanzhou University, Lanzhou
  • Received:1986-07-08 Online:1987-11-24 Published:1987-11-24

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被引次数

35

摘要： 制备了十五种稀土与2-苯基喹啉-4-甲酸的配合物,确定其组成为REA3·2H2O(RE=Y,La-Nd,Sm-Lu,A=C16H10NO2-);研究了IR、UV、H-NMR、分子荧光光谱、摩尔电导、溶解性及热稳定性等。

Abstract: The fifteen complexes of rare earth with 2-phenyl-quinoline-4-carboxylic acid have been prepared. The composition of complexes has been determined as RE(C16H10NO2-)3·H20(RE =Y,La-Nd, Sm-Lu). The IR, UV, H-NMR, TG and DTA, molecular fluorescence spectra, molecular conductance of these complexes in DMF and DMSO, and their solubilities in H2Oand organic solvents of the complexes have also been studied.

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