聚乙炔膜的稳定化

高等学校化学学报 ›› 1987, Vol. 8 ›› Issue (11): 1038.

聚乙炔膜的稳定化

杨慕杰, 余小春, 刘明, 沈之荃

浙江大学化学系

收稿日期:1986-05-13 出版日期:1987-11-24 发布日期:1987-11-24

Stabilization of Polyacetylene Films

Yang Mujie, Yu Xiaochun, Liu Ming, Shen Zhiquan

Department of Chemistry, Zhejiang University, Hangzhou

Received:1986-05-13 Online:1987-11-24 Published:1987-11-24

摘要/Abstract

摘要： 四种抗氧剂(A、M、RDH、264)中,AM是能添加入聚乙炔膜内的一种有效抗氧剂。用氧化增重和红外分析研究了四种聚乙炔膜(PA,PA/SBR,PA/AM,PA/SBR/AM)暴露于空气中的氧化及异构化动力学行为。研究表明,各种膜在室温(25℃)空气中的耐氧化性能和抗异构化能力的次序相同:PA/SBR/AM>PA/AM>PA/SBR>PA。添加抗氧剂AM于聚乙炔中,不影响掺杂聚乙炔的优良电性能及其它性能。

Abstract: From a comparison of several antioxidants(AM,RD,Hand 264), AMis a powerful antioxidant which can be added into polyacetylene(PA). The kinetics of oxidation and isomerization of PA, PA/SBR, PA/AM, and PA/SBR/AM films have been established by oxidation-weight gain and infrared spectro-photometric analyses. Oxidation of all films is a first-order process comprised of one or two distinct regions. The induction period of oxidation for PA/SBR/AM film is the longest of all films cis-trans isomerization of PAfilms also shows two or three first-order kinetic regions. The antioxidation and anti-isomerization ability of various PAfilms exposed to air at 25℃ decreased in the following order:PA/SBR/AM>PA/AM>PA /SBR>PA. The addition of AMhas no influence on the conductivity possessed by doping PA. It is of significance for use of PAin industry.

TrendMD:

杨慕杰, 余小春, 刘明, 沈之荃. 聚乙炔膜的稳定化. 高等学校化学学报, 1987, 8(11): 1038.

Yang Mujie, Yu Xiaochun, Liu Ming, Shen Zhiquan . Stabilization of Polyacetylene Films. Chem. J. Chinese Universities, 1987, 8(11): 1038.