高等学校化学学报 ›› 1987, Vol. 8 ›› Issue (10): 863.

• 论文 •    下一篇

二(2-乙基已基)二硫代磷酸合钴(Ⅱ)配合物氧化作用的研究

黄锦汪, 夏敬谋, 杨学强, 陈美延, 计亮年   

  1. 中山大学化学系
  • 收稿日期:1986-03-25 出版日期:1987-10-24 发布日期:1987-10-24

A Study of Oxidation of Complex of Cobalt(Ⅱ) with Bis(2-Ethylhexyl)Dithiophosphoric Acid

Huang Jinwang, Xia Jingmou, Yang Xueqiang, Chen Meiyan, Ji Liangnian   

  1. Department of Chemistry, Zhongshan University, Guangzhou
  • Received:1986-03-25 Online:1987-10-24 Published:1987-10-24

摘要: 通过紫外可见光谱,红外光谱及磁化率的测定,研究了二(2-乙基己基)二硫代磷酸合钴(Ⅱ)配合物的氧化作用。

Abstract: The oxidation of the complex of cobalt (Ⅱ) with bis(2-ethylhexyl) dithio-phosphoric acid has been studied by means of UVspectra, infrared spectra, and magnetic susceptibility. The results revealed that there is a σ-π bond between cobaltous and sulfur atoms.The cause of oxidation of the complex was interpreted in terms of the electronegativity.

TrendMD: