高等学校化学学报

高等学校化学学报 ›› 1987, Vol. 8 ›› Issue (1): 55.

• 论文 • 上一篇    下一篇

热动力学的研究(Ⅴ)--二级反应的热动力学研究法

吴小平1, 秦自明1, 邓郁1, 蔡汝尊2   

  1. 1. 四川大学化学系;
    2. 成都大学化学系
  • 收稿日期:1985-10-23 出版日期:1987-01-24 发布日期:1987-01-24
  • 基金资助:

    国家教育委员会科学基金

Studies on Thermokinetics(Ⅴ)--Thermokinetic Method for the Second Order Reactions

Wu Xiaoping1, Qin Ziming1, Deng yu1, Cai Ruzen2   

  1. 1. Department of Chemistry. Sichuan University, Chengdu;
    2. Department of Chemistry, Ghengdu University, Chengdu
  • Received:1985-10-23 Online:1987-01-24 Published:1987-01-24

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摘要： 根据热动力学的基础理论,本文建立了二级反应的无量纲参数法。通过对两个化学反应体系的热动力学研究,验证了这种无量纲参数法的基础理论方程。

Abstract: On the theoretical basis of thcrmokinetics proposed in previous article, the method of dimensionless paramter for second order reactions are derived in thispaper.This method has been used to study the saponification of two csters in aqueous alcohol solvents. The rate constants of these reactions calculated with this method are in agreement with the values in literatures. And therefore, the fundamental equations of thermokinctic method for second order reactions are believed to be correct.

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