高等学校化学学报 ›› 1986, Vol. 7 ›› Issue (9): 770.

• 研究简报 • 上一篇    下一篇

镧系离子(Nd3+、Ho3+、Er3+)与PMHFP和DAM三元配合物的制备及超灵敏跃迁的研究

钱博1, 赵忠顺1, 张进胜1, 刘谦光1, 李聚源2   

  1. 1. 陕西师范大学化学系;
    2. 中国人民武装警察部从技术学院
  • 收稿日期:1985-05-24 出版日期:1986-09-24 发布日期:1986-09-24

Studies on Preparation and Hypersensitive Transition for the Ternary Coordination Compounds of Lanthanide Ions (Nd3+, Ho3+,Er3+) with PMHFP and DAMStudies on Preparation and Hypersensitive Transition for the Ternary Coordination Compounds of Lanth

Qian Bo1, Zhao Zhongshun1, Zhang Jinsheng1, Liu Qianguang1, Li Juyuan2   

  1. 1. Department of Chemistry, Shanxi, Normal University, Xi'an;
    2. The Technical Academy of the Chinese people's Armed Police Force, Xian
  • Received:1985-05-24 Online:1986-09-24 Published:1986-09-24

摘要: 镧系离子(Ln3+)同二安替吡啉甲烷(DAM)和1-苯基-3-甲基-4-苯甲酰基吡唑酮-5等β-二酮形成的三元配合物的超灵敏跃迁现象已有研究[1-3]。Ln3+同1-苯基-3-甲基-4-七氟丁酰基吡唑酮-5(PMHFP)的二元配合物已经合成[4]。本文研究Ln3+)-PMHFP-DAM体系中的超灵敏跃迁现象及其三元配合物的组成、结构和性质。

Abstract: The ternary coordination compounds of Lanthanidc ions (Nd3+,Ho3+,Er3+) with 1-phcnyl-3-methyl-4-heptaflurobutyryl-pyrazolone-5(PMHFE)and diantipyryl methane (DAM) in water-ethanolic solution were studied by using spectrophotomc-try.The corresponding coordination compound of neodymium was prepared in solid state and characterized with elemental analyses and infrared.Us composition is Nd(C14H8O2N2F7)3·C23H23N4O3

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