高等学校化学学报

高等学校化学学报 ›› 1986, Vol. 7 ›› Issue (7): 605.

• 研究论文 • 上一篇    下一篇

卤代苯甲酰二茂铁及其还原产物—相应醇的研究

张玉鸿1, 赵建国1, 师树简1, 陈寿山2   

  1. 1. 内蒙古大学化学系;
    2. 南开大学元素有机化学研究所
  • 收稿日期:1985-03-26 出版日期:1986-07-24 发布日期:1986-07-24
  • 基金资助:

    中国科学院科学基金

The Study on Halogen Substituted Benzoylferrocenes and Their Reduction Products—Corresponding Alcohols

Zhang Yuhung1, Zhang Jiankuo1, Shi Shujian1, Chen Shoushan2   

  1. 1. Department of Chemistry, Inner Mongolia Unitersity, Huhehot;
    2. Institute of ElementO-argarie Chemistry, Nankai University, Tiaijin
  • Received:1985-03-26 Online:1986-07-24 Published:1986-07-24

PDF (PC)

摘要： 用二茂铁和卤代苯甲酰氯通过付-克反应合成了十二个邻、间、对的卤代苯甲酰二茂铁,用LiAlH4或KBH4还原可得相应的卤代苯甲酰二茂铁的醇。其中有十六个是新化合物,并对它们的IR和1HNMR谱的性质进行了初步的讨论。

Abstract: All of the o,m,p-halogen substituted benzoylferrocenes have been prepared from ferrocene and halogen substituted benzoylchloride by Frieded-Crafts acylation.The ketenes were reduced to the corresponding halogen substituted phenylferrocenyl-methanols with LiAlH4 or KBH4 Sixteen of them are new compounde.The sythesis results and characteristics of IRand 1H NMRspectra of all the above mentioned compounds were preliminarily discussion.

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