α,β,γ,δ-四-(4-甲基苯基)卟啉与铜反应的分光光度法研究

高等学校化学学报 ›› 1986, Vol. 7 ›› Issue (7): 597.

α,β,γ,δ-四-(4-甲基苯基)卟啉与铜反应的分光光度法研究

何淑琼, 黄泽兴, 肖建洪

华侨大学化学系

收稿日期:1985-01-04 出版日期:1986-07-24 发布日期:1986-07-24

Synthesis of α, β,γ,δ Tetra (4-Methylphenyl) Porphine and Spectrophotometric Study of the Reaction Between Copper

He Shuqiong, Huang Xexin, Xiao Jianhong

Department or Chemistry, Huaqiao University , Quanhou

Received:1985-01-04 Online:1986-07-24 Published:1986-07-24

摘要/Abstract

摘要： 目前,已见报导用非水溶性卟啉化合物测定铜的有:TPP^[1.2]、TF(cooEt)P^[3]。本文研究了在表面活性剂存在下,非水溶性卟啉TTP与铜络合反应的条件,试验了多种离子和盐的干扰情况。结果表明,此方法灵敏度较高(ε₄₁₄=4.5×10⁵),准确性较好,操作简便,可用于水样、铝合金和矿石中微量铜的直接测定。

Abstract: In this paper,α,β,γ,δ-tclra-(4-methylphenyl) porphinc(TTP) has been prepared by the reaction of 4-tolualdehyde with pyrrole.The complex formation reaction of TTPwith coppcr(Ⅱ) in the presence of anionic surfactant,sodium dodecyl benzene sulf'onate has been studied.The water-insoluble TTPwas found to be a highly sensitive and highly selective reagent for direct spcctropliolomclric determination of ultramicro amount of copper.The Soret band of coppcr(Ⅱ)-TTPcomplex lies at 414nm,which was well separated from that of diacid form of TTP (444).The composition of the complex is coppcr(Ⅱ) TTP=1:1.Apparent molar absorption coefficient is 4.5×10⁵.The interference of 23 ions and 6 salts was examined and found to be mininal.This simple and rapid method has been used for the analysis of copper in water sample,ores and Al alloy with satisfactory results.

TrendMD:

何淑琼, 黄泽兴, 肖建洪. α,β,γ,δ-四-(4-甲基苯基)卟啉与铜反应的分光光度法研究. 高等学校化学学报, 1986, 7(7): 597.

He Shuqiong, Huang Xexin, Xiao Jianhong . Synthesis of α, β,γ,δ Tetra (4-Methylphenyl) Porphine and Spectrophotometric Study of the Reaction Between Copper. Chem. J. Chinese Universities, 1986, 7(7): 597.