高等学校化学学报 ›› 1986, Vol. 7 ›› Issue (6): 519.
• 研究简报 • 上一篇 下一篇
尹承烈1, 俞稼镛2, 王涵慧2, 李宗琦2, 康致泉2
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Yin Chenglie1, Yu Jiayong2, Wang Hanhui2, Li Zongqi2, Kang Zhiquan2
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摘要: 我们曾报导[1]用光学活性试剂α-乙酰氧基-L-丙酰氯与外消旋2-丁醇反应,生成相应的一对非对映异构体酯,经气液分配色谱作定量测定,达到快速、微量分析其旋光异构体含量的目的。
Abstract: Arapid and microanalytical method has been developed by using gas chromato-graphymass spectrometry for quantifying racemic-2-octanol, which can be easily converted to its diastereoisomer by treatment with a-acetyl-L-propionyl chloride in the presence of pyridine.The enantiomers of 2-octanol were separated as their a-acetyl-L-propionic ester derivatives on a capillary column coated with SE-30 or squalane as the stationary phase.
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尹承烈, 俞稼镛, 王涵慧, 李宗琦, 康致泉. 用气液分配色谱对外消旋2-辛醇的析解. 高等学校化学学报, 1986, 7(6): 519.
Yin Chenglie, Yu Jiayong, Wang Hanhui, Li Zongqi, Kang Zhiquan. Resolution of Diastereoisomeric 2-Octanol by Glass Capillary Gas Chromatography. Chem. J. Chinese Universities, 1986, 7(6): 519.
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http://www.cjcu.jlu.edu.cn/CN/Y1986/V7/I6/519