高等学校化学学报 ›› 1986, Vol. 7 ›› Issue (5): 397.

• 研究论文 • 上一篇    下一篇

硝酸铈(Ⅳ)与四氧二氮环醚配合物

朱文祥, 李琴, 张爱军, 陈伯涛, 赵继周, 金林培   

  1. 北京师范大学化学系
  • 收稿日期:1985-03-13 出版日期:1986-05-24 发布日期:1986-05-24
  • 基金资助:

    中国科学院科学基金

Complex of Cerium(Ⅳ) Nitrate with a Tetraoxadiaza Macrocycle

Zhu Wenxiang, Li Qin, Zhang Aijun, Chen Botao, Zhao Jizhou, Jin Linpei   

  1. Department of Chemistry, Beijing Normal University, Beijing
  • Received:1985-03-13 Online:1986-05-24 Published:1986-05-24

摘要: 本文报道通过中间配合物Ce(OPPh3)2(NO3)4与1,7,10,16-四氧-4,13-二氮杂环十八烷作用制得一组成为Ce(C13H26N2O4)(NO3)4·2.5(CH3COCH3)的黄色固体配合物。该配合物在空气中稳定,在大多数有机溶剂中不溶解,但可溶于DMSO中。运用电导、波谱技术对该配合物的性质进行了研究。

Abstract: The 1: 1 solvated complex of cerium( Ⅳ ) nitrate with a tctraoxadiaza 18-membered. macrocycle has been synthesized under anhydrous conditions. The complex was characterized by elemental analysis, conductometric and spectral data. The properties of the complex has been studied.

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