高等学校化学学报

高等学校化学学报 ›› 1986, Vol. 7 ›› Issue (4): 322.

• 研究简报 • 上一篇    下一篇

(烷基环戊二烯基)环戊二烯基二氯化钛的合成与反应

陈寿山, 李金山, 王积涛   

  1. 南开大学元素有机化学研究所
  • 收稿日期:1984-11-20 出版日期:1986-04-24 发布日期:1986-04-24
  • 基金资助:

    中国科学院科学基金

Synthesis and Reaction of (Alkylcyclopentadienyl) Cyclopentadienyltitanium Dichloride

Chen Shoushan, Li Jinshan, Wang Jitao   

  1. Institute of Elemento-Organio Chemistry, Nankai University, Tianjin
  • Received:1984-11-20 Online:1986-04-24 Published:1986-04-24

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摘要： Richard在1959年合成了第一个环戊二烯基(取代环戊二烯基)钛衍生物,(CH3C5H4)(C5H5)T1Cl2[1].我们曾报道了环戊二烯基(烯烃基环戊二烯基)二卤化钛的合成和反应[2]。

Abstract: The (alkylcyclopentadienyl)cyclopcntadienyltitamum dichloridc, (η5-RC5H4)· C5H5TiCl2 (where R = CH5, C2H5, n-C5H7, n-C4H9, n-C5H11) have been prepared. By exchange reaction of halogen, the corresponding difluoride, dibro-mide and dithiocyanide have been obtained. Their 1H NMRspectrum has also been studied.

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