高等学校化学学报 ›› 1986, Vol. 7 ›› Issue (4): 305.

• 研究论文 • 上一篇    下一篇

示波极谱滴定的研究(ⅩⅩⅨ)—双微铂电极上的示波极谱络合滴定法

杨昭亮, 高鸿   

  1. 南京大学化学系
  • 收稿日期:1984-11-12 出版日期:1986-04-24 发布日期:1986-04-24
  • 基金资助:

    中国科学院科学基金

Investigations on Oscillopolarographic Titrations(XXⅨ)—Oscillopolarographic Chelometric Tirations on Two Micro Pt-Electrodes

Yang Zhaoliang, Gao Hong(H. Kao)   

  1. Department of Chemistry, Nanjing University, Nanjiny
  • Received:1984-11-12 Online:1986-04-24 Published:1986-04-24

摘要: 本文提出双微铂电极示波极谱滴定法。在KCl存在时,氨羧络合剂在双微铂电极示波极谱图上有敏锐切口,可以用来指示络合滴定的终点。方法准确度和精密度都符合容量分析要求。

Abstract: Up to now, all oscillopolarographic litrations were carried out in electrolytic cells with one micro electrode and one macro electrode. Oscillopolarographic titrations on two similar micro indicator electrodes have been studied and it was found that many substances such as EDTAand its related compounds giving no incisions on one micro Pt-electrodc showed distinct incisions on two micro Pt-clectrodes. For example, in the presence of KC1, EDTAand its related compounds yielded distinct incisions which can be used to indicate end-points of many chclometric titrations. Th4+, In3+, Ga3+, Zn2+ , Ni2+, Co2+, Mn2+, Cd2+, and rare earths can be directly titrated with EDTA, DTPA, CYDTA, and HEDTA. Many new chelomctric titration procedures were developed.

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