高等学校化学学报

高等学校化学学报 ›› 1986, Vol. 7 ›› Issue (3): 261.

• 研究论文 • 上一篇    下一篇

硫酸根·水·2,3-二甲基-2,3-丁二胺合铂的晶体结构和分子结构

郭东跃1, 王风山1, 曲筠2, 唐雯霞2   

  1. 1. 吉林大学理论化学研究所;
    2. 南京大学配位化学研究所
  • 收稿日期:1984-11-01 出版日期:1986-03-24 发布日期:1986-03-24

Crystal Structure of Sulfatoaquo-2,3-Dimethyl-2,3-Butyldiamineplatinum

Guo Dongyue1, Wang Fengshan1, Qu Yun2, Tang Wenxia2   

  1. 1. Institute of Theor. Ghem, of Jilin University, Changchun;
    2. Institute of Coordination Chemistry of Nanjing University, Nanjing
  • Received:1984-11-01 Online:1986-03-24 Published:1986-03-24

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摘要： 硫酸根·水·2,3-二甲基-2,3-丁二胺合铂晶体属正交晶系,空间群C2cb;晶胞参数a=11.073(3)Å,6=9.672(2)Å,c=21.156(7)Å;Z=8,衍射强度数据系在NicoletXRDR3四圆衍射仪上收集,结构参数经块矩阵最小二乘法精修后,R值为0.0716。

Abstract: [Pt DMBA SO4H2O]·H2Ocrystals belong to orthorhombic system, a= 11.073 (3), b = 9.672(2), c=21.156(7)Å, space group C2cd, Z = 8. The diffraction data (MoKa) were collected with Nicolet R3 fourcircle diffractometer. The structure was determined by heavy atom method and refined by the least square program, R = 0.0716.

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