高等学校化学学报

高等学校化学学报 ›› 1986, Vol. 7 ›› Issue (3): 228.

• 研究论文 • 上一篇    下一篇

水稻二化螟拟信息素的合成

李正名, 刘天麟, 刘子平, 郭虎森, 幺恩云   

  1. 南开大学元素有机化学研究所
  • 收稿日期:1984-11-16 出版日期:1986-03-24 发布日期:1986-03-24
  • 基金资助:

    中国科学院科学基金

The Synthesis of the Parapheromones of Rice Stem Borer Moth,Chilo Suppressalis

Li Zhengming, Liu Tianlin, Liu Ziping, Go Husen, Yao Enyun   

  1. The iiesearch Institute of Elemento-Organic Chemistry, Nankai University, Tianjin
  • Received:1984-11-16 Online:1986-03-24 Published:1986-03-24

PDF (PC)

被引次数

7

摘要： 通过烷叉三苯基膦烷与脂肪醛或芳香醛的Wittjg反应,立体选择性地制备了(Z)-十六碳烯及其环氧化合物、芳基类似物,顺-5-十六碳烯经溴加成,氨基钠/液氨中退减—还原转变成反-5-十六碳烯,上述化合物对二化螟触角电位具有生物活性。

Abstract: (Z)-Hcxadeccnes, their cpoxidcs and aryl analogs have stcrcospccifically been prepared by Wittig reaction of alkylidenetriphenylphosphorancs with alkylaldehydcs or arylaldehydes, respectively. (E)-5-Hexadecene is obtained from the conversions of (Z)-5-hcxadccenc via the addition of bromine and then elimination-reduction with NaNH2/NH3(1). These compounds arc active in EAGresponses.

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