高等学校化学学报 ›› 1986, Vol. 7 ›› Issue (12): 1150.

• 研究论文 • 上一篇    

几种新的四苯(基)苯基有机硅化合物的研究

陈剑华, 冯圣玉, 杜作栋   

  1. 山东大学化学系
  • 收稿日期:1985-07-22 出版日期:1986-12-24 发布日期:1986-12-24

Syntheses of New Tetraphenylphenylorganosilicon Compounds

Chen Jianhua, Feng Shengyu, Du Zuodong   

  1. Department of Chemistry, Shandong University, Jinan
  • Received:1985-07-22 Online:1986-12-24 Published:1986-12-24

摘要: 本工作以双乙烯基四甲基二硅氧烷、乙烯基甲基二氯硅烷、乙烯基七甲基环四硅氧烷分别与四苯基环戊二烯酮通过Diels-Alder反应合成了相应的四种四苯(基)苯基有机硅化合物(Ⅰ—Ⅳ)。并由化合物Ⅲ又制成了三种化合物Ⅴ一Ⅶ。对这些新化合物的组成、结构作了相应的分析、测试和鉴定。还对有些Diels-Alder反应做了改进,从封管反应改为常压反应后,效果更佳。

Abstract: The following new tetraphetlylphenylsilicon compounds have been synthesized by Diels-Alder reaction;(Ⅰ)bis(tetraphenylphenyl)tetramethyldisiloxane,(Ⅱ)tetraphenylphenylvinyltetramethyldisiloxane,(Ⅲ)tetraphenylphenylmethyldichloro-silane,(Ⅳ)tetraphenylphenylheptamethylcyclotetrasiloxane,(Ⅴ)tetraphenyl phenyl-methylsilanediol,(Ⅵ)trimethyltri(tetraphenylphenyl)cyclotrisiloxane,(Ⅶ)etramethyltctra(tetraphenylphenyl)cyclotetrasiloxane.Structure and composition of compounds(Ⅰ-Ⅶ)were determined by spectral analyses.

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