高等学校化学学报 ›› 1986, Vol. 7 ›› Issue (11): 989.

• 研究简报 • 上一篇    下一篇

电滴定分析的新方法

徐伟建, 高鸿   

  1. 南京大学化学系
  • 收稿日期:1985-07-12 出版日期:1986-11-24 发布日期:1986-11-24
  • 基金资助:

    中国科学院科学基金

New Techniques in Electrometric Titration

Xu Weijian, Gao Hong   

  1. Department of Chemistry, Nanjing University, Nanjing
  • Received:1985-07-12 Online:1986-11-24 Published:1986-11-24

摘要: 利用示波极谱图上切口的出现或消失来指示滴定终点的示波极谱滴定法具有终点直观、操作简便和抗干扰能力强等优点。但该法要求试剂(滴定剂、被滴物或指示剂)能在示波极谱图上产生敏锐切口才能应用。

Abstract: Five new techniques in electrometric titration are described.They are:Ⅰ Oscillopolarographic titration at 1 micro and 1 macro Pt-electrodes.Ⅱ.Oscillopolarographic titration at 3 electrodes.Ⅲ.Oscillo-potentiometric titration at 3 electrodes.Ⅳ.Oscillo-potentiometric titration at 1 micro and 1 macro Pt-electrodes.V.A.C.Oscillo-potentiomctric titration at 2 macro Pt electrodes.The methods Ⅰ and Ⅱ use the abrupt change of oscillopolarogram to indicate end-point but do not require the oscillopolarograms to have a sensitive incision.The others do not use any oscillopolarogram but use the abrupt potential change between electrodes.Five new techniques in electrometric titration are described.They are:Ⅰ Oscillopolarographic titration at 1 micro and 1 macro Pt-electrodes.Ⅱ.Oscillopolarographic titration at 3 electrodes.Ⅲ.Oscillo-potentiometric titration at 3 electrodes.Ⅳ.Oscillo-potentiometric titration at 1 micro and 1 macro Pt-electrodes.V.A.C.Oscillo-potentiomctric titration at 2 macro Pt electrodes.The methods Ⅰ and Ⅱ use the abrupt change of oscillopolarogram to indicate end-point but do not require the oscillopolarograms to have a sensitive incision.The others do not use any oscillopolarogram but use the abrupt potential change between electrodes.

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