非水溶性meso-四-(4-乙酰氧基苯)卟啉的合成及其与铅显色反应的研究

高等学校化学学报 ›› 1986, Vol. 7 ›› Issue (10): 886.

非水溶性meso-四-(4-乙酰氧基苯)卟啉的合成及其与铅显色反应的研究

王东进¹, 金昌铭¹, 陈天富¹, 黄泽兴², 何淑琼²

1. 福州大学化学系;
2. 华侨大学化学系

收稿日期:1985-08-08 出版日期:1986-10-24 发布日期:1986-10-24

The Synthesis of Meso-Tetrakis-(4-Acetyloxylphenyl) Porphine and the Spectrophotometric Study of Its Colour Reaction with Lead

Wang Dongjin¹, Jin Changming¹, Chen Tianfu¹, Huang Zexing², He Shuqiong²

1. Department of Chemistry, Fuzhou University, Fuzhou;
2. Department of Chemistry, Huaqiao University, Quanzhou

Received:1985-08-08 Online:1986-10-24 Published:1986-10-24

摘要/Abstract

摘要： 目前在用水溶性卟啉衍生物作显色剂方面已有文献总结^[1]。但对非水溶性卟啉则研究得较少。就测定痕量铅而言,皆用水溶性卟啉衍生物,而用非水溶性卟啉测定铅,则尚未见报导^[2-6]。

Abstract: The water-insoluble porphine,meso-tetrakis-(4-acetyloxylphenyl)porphine(T(4-AOP)P),has been synthesized and its colour reaction with lead(Ⅱ)has been studied.The lead(Ⅱ)complex was formed in the presence of sodium dode-cyl sulfate.The complex formation was slow at room temperature,however,it could be accelerated by heating at 100℃ for 12 min.The soret band of the complex lies at 466nm,which is well separated from that7 of the reagent(420nm)at pH9.5.Apparent molar absorptivity of the complex is 2.6×10⁵ lmol^-1 cm^-1.Beer's law is obeyed in the rang of 0-6μg/10ml for lead(Ⅱ).Tolerance limits were shown for 24 ions.The method established could be applied to the ditect determination of lead(Ⅱ)in sodium chloride with satisfactory result.

TrendMD:

王东进, 金昌铭, 陈天富, 黄泽兴, 何淑琼. 非水溶性meso-四-(4-乙酰氧基苯)卟啉的合成及其与铅显色反应的研究. 高等学校化学学报, 1986, 7(10): 886.

Wang Dongjin, Jin Changming, Chen Tianfu, Huang Zexing, He Shuqiong. The Synthesis of Meso-Tetrakis-(4-Acetyloxylphenyl) Porphine and the Spectrophotometric Study of Its Colour Reaction with Lead. Chem. J. Chinese Universities, 1986, 7(10): 886.