高等学校化学学报

高等学校化学学报 ›› 1986, Vol. 7 ›› Issue (1): 7.

• 研究论文 • 上一篇    下一篇

尾式卟啉铁一氧化碳配合物性质研究

曹锡章, 牟西海   

  1. 吉林大学化学系
  • 收稿日期:1984-08-27 出版日期:1986-01-24 发布日期:1986-01-24

Studies on Carbon Monoxide Complex of a New Tailed Porphyriniron

Cao Xizhang, Mu Xihai   

  1. Department of Chemistry, Jilin University, Changchun
  • Received:1984-08-27 Online:1986-01-24 Published:1986-01-24

PDF (PC)

被引次数

10

摘要： 一种新型的第五配位基为叔胺的尾式卟啉铁(间—(邻-(4-二乙胺基丁酰胺基(苯基)三苯基卟啉合铁(Ⅱ),meso-MDBPTPPFe(Ⅱ))同CO反应生成配合物,用分光光度法测定了配合物的平衡常数,解释了可见紫外光谱的位移现象,用红外差谱方法测得CO的伸缩振动频率是1961cm-1。

Abstract: The carbon monoxide adduct of Fe complex of meso-mono[o-(4-dietheyla-mino) butyramidophenyl] triphenylporphyrin (tailed porphyrin, meso-MDBPTPP) is reported. The equilibrium constant of the adduct was measured by spectrophoto-metric method and the COvibration was obtained by using differential spectrum technique. Experimental results demonstrate that the fifth ligand affects the equilibrium constant dramatically.

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