高等学校化学学报

高等学校化学学报 ›› 1986, Vol. 7 ›› Issue (1): 36.

• 研究论文 • 上一篇    下一篇

苯并噻唑酮的磷酰化反应

陈克俭, 张景龄   

  1. 华中师范学院农药化学研究所
  • 收稿日期:1984-08-25 出版日期:1986-01-24 发布日期:1986-01-24
  • 基金资助:

    中国科学院科学基金

Phosphorylation Reactions of Benzothiazolone

Chen Kejian, Zhang Jingling   

  1. Research Institute of Pesticide Chemistry, Huazhong Normal University, Wuhan
  • Received:1984-08-25 Online:1986-01-24 Published:1986-01-24

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摘要： 本文研究了苯并噻唑酮与亚磷酸酯,六烷基亚磷酰胺及双-(二烷基胺基)苯基膦的反应,发现它不能与各种亚磷酸酯发生反应,与亚磷酰胺等反应生成N-磷酰化产物,在室温下观察到了P—N健的旋转阻滞现象,并对这种现象进行了讨论。

Abstract: This paper reports the reactions of benzothiazolone with phosphites, hexaalkyl phosphorous amides and bis-(dialkylamino)-phenylphosphines. Benzothiazolone could not react with various phosphites, but it gave N-phosphorylated products with phosphorous amides. The restricted rotation about P-Nbond at room temperature was observed and discussed.

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