高等学校化学学报

高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (9): 816.

• 研究论文 • 上一篇    下一篇

配位场的中间场研究

龙翔云1, 李伯符2, 孙家钟2   

  1. 1. 中南民族学院;
    2. 吉林大学理论化学研究所
  • 收稿日期:1983-12-09 出版日期:1985-09-24 发布日期:1985-09-24

The Research on Intermediate Field of Ligand Field Theory

Long Xiangyun1, Li Baifu2, Sun Chia-chung2   

  1. 1. South-Central Institute for National Minorities;
    2. Institute of Theoretical Chemistry, Jilin University, Changchun
  • Received:1983-12-09 Online:1985-09-24 Published:1985-09-24

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摘要： 在忽略电子组态间相互作用下取中间场全分析本征函数展开式中两、三项来计算配位场能级,得到接近全分析的结果,建立了配位场能级相关图;提出了划分配位场的弱场,中间场和强场区的一个方法;指出第一过渡族元素络合物多属中间场络合物。

Abstract: The ligand field energy has been calculated in this paper. Taking two or three terms from the eigenvalue function expansion of intermediate field under condition of neglecting the interaction of different configurations, the result approaching that from total analysis has been obtained.The energy level correlatograph of ligand fielld has also been established and a method to delimit the areas of weak, intermediate and strong field has been proposed.It is found that many complexes of transition metals of the 4th period,especialy those of iron group elements, are intermediate compexes.

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