高等学校化学学报

高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (9): 783.

• 研究论文 • 上一篇    下一篇

玻炭汞膜电极多阶半微分溶出曲线的理论方程式

王耀光   

  1. 福州大学化学系
  • 收稿日期:1984-05-04 出版日期:1985-09-24 发布日期:1985-09-24

Theoretical Curve Equations of Multiple Semidifferential Anodic Stripping Electroanalysis with Thin Mercury Film Electrode Formed in Situ

Wang Yaoguang   

  1. Department of Chemistry, Fuzhou University, Fuzhou
  • Received:1984-05-04 Online:1985-09-24 Published:1985-09-24

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摘要： 本文建立了汞膜电极阳极溶出多阶半微分电分析法理论的基本数学模型,借助电子计算机,直接描绘出其理论曲线,并给出有关特征参数,计算结果与实验验证表明,本文所推导的理论曲线方程式是正确的。

Abstract: The theoretical curves which describe the 1.5th order derivative, e', and 2.5th order derivative of current, e", vs. the electrode potential, E,are presented In anodic stripping processes at thin mercury film formed in situ on the rotating glassy carbon disk electrode. The theoretical curve equations are.whereandwhereThe numerical calculations have been programmed in BASIClanguage for computation with APPLE II PLUSmicrocomputer in accordance with above equat-ions.

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