高等学校化学学报

高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (8): 735.

• 研究论文 • 上一篇    下一篇

三氯化钕异丙醇络合物的晶体结构和分子结构

金钟声1, 王生龙1, 王佛松1, 申成2, 杨光第2, 樊玉国2   

  1. 1. 中国科学院长春应用化学研究所;
    2. 吉林大学理论化学研究所
  • 收稿日期:1984-03-16 出版日期:1985-08-24 发布日期:1985-08-24

The Crystal and Molecular Structure of Neodymium Chloride Isopropyl Alcohol Complex

Jin Zbongsheng1, Wang Shenglong1, Wang Fusong1, Shen Cheng2, Yang Guangdi2, Fan Yuguo2   

  1. 1. Changchun Institute of Applied Chemistry, Academic Sinica;
    2. Institute of Theoretical Chemistry of Jilin University, Changchun
  • Received:1984-03-16 Online:1985-08-24 Published:1985-08-24

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被引次数

4

摘要： 本文报导了X射线衍射法确定的三氯化钕异丙醇络合物[NdCl3·(CH3CHOHCH3)3]2的晶体结构。在晶体中每二个钕离子通过二个氯离子形成的氯桥相联,组成一个双核稀土络合物分子。其中每个Nd离子是七配位的。

Abstract: The crystal structure of [NdCl5·(CH5CHOHCH3)]2 has been determined by X-ray diffraction method. It is triclinic and the space group is P1, with dimensions: a= 11.184(2)Å, b= 13.462(3)Å,c = 5.9794(9)Å, α = 101.37(2) °β = 93.6l(2)°,γ= 69.46(2)°. The structure was solved by patterson method. The final residual factor is R= 0.038. The feature of the crystal structure is that every two Nd ions are linked in pairs through a chlorine bridge o?two chlorine ions to form a complex molecule and every Nd ion is seven-coordinate.

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