高等学校化学学报

高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (8): 714.

• 研究论文 • 上一篇    下一篇

热动力学的研究(Ⅱ)——一级反应的热动力学研究法

邓郁1, 徐映宏2   

  1. 1. 四川大学化学系;
    2. 新疆师范大学化学系
  • 收稿日期:1984-03-28 出版日期:1985-08-24 发布日期:1985-08-24
  • 基金资助:

    教育部科学基金

Studies on Thermokinetics (Ⅱ)——Thermokinetic Method for the First Order Reactions

Deng Yu1, Xu Yinghong2   

  1. 1. Department of Chemistry, Sichuan University, Chengdu;
    2. Department of Chemistry, Xinjiang Normal University , Wulumuqi
  • Received:1984-03-28 Online:1985-08-24 Published:1985-08-24

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摘要： 本文用无量纲参数法研究了两个反应体系的热动力学,验证了无量纲参数法的基础理论方程。

Abstract: On the theoretical basis of thermokinetics proposed in previous article, the fundamental equations of thermokinetic method for the first order reactions are derived in this paper.This method has been used to study the saponification of two esters in aqueous alcohol solvents. The rate constants of these reactions claculated with this method are in agreement with the values in literatures. And therefore, the theoretical basis of this method is believed to be correct.

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