高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (8): 663.

• 研究论文 •    下一篇

硼化合物研究(ⅩⅣ)——含硼双(π-芳烃)铁(Ⅱ)化合物的合成与性质

张伦, 方新钦, 张国敏   

  1. 武汉大学化学系
  • 收稿日期:1984-03-14 出版日期:1985-08-24 发布日期:1985-08-24
  • 基金资助:

    中国科学院科学基金

Study on Boron Compounds (ⅩⅣ)——Synthesis and Properties of Boron-Containing Bis(π-Arene) Iron (Ⅱ) Compounds

Zhang Lun, Fang Xinqin, Zhang Guomin   

  1. Department of Chemistry, Wuhan University, Wuhan
  • Received:1984-03-14 Online:1985-08-24 Published:1985-08-24

摘要: 合成了13个新的双(π-芳烃)铁(Ⅱ)化合物,对它们进行了元素分析和红外光谱测定,部分化合物还做了质谱和1H核磁共振谱的鉴定。通过DTATG法,研究了化合物的热行为。

Abstract: Thirteen bis(π-arene) iron (Ⅱ) compounds of [Ar2Fe]B12H12 and [Ar2Fe] (PF6)2 were synthesized, and these compounds have all been identified by elemental analysis and IRspectra, and some of them by MSand 1H NMR.The thermal behavior of these compounds has been investigated by DTA-TGmethod and IRspectroscopy, and their thermal stability is described.

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