高等学校化学学报

高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (7): 613.

• 研究论文 • 上一篇    下一篇

锕系元素有机化合物研究(Ⅱ)——新的钍夹心物的合成和结构鉴定

王序昆1, Streitwieser2   

  1. 1. 南开大学元素有机化学研究所;
    2. 美国加利福尼亚大学贝克莱分校化学系
  • 收稿日期:1984-03-05 出版日期:1985-07-24 发布日期:1985-07-24

Studies on Organoactinide Compounds (Ⅱ)——Synthesis and Structural Characterization of Some New Substituted Thorocene

Wang Xukun1, Streitwieser2   

  1. 1. Institute of Elementoorganic Chemistry, Nankai University, Tianjing;
    2. Department oj Chemistry, University of California, Berkeley, U. S.A.
  • Received:1984-03-05 Online:1985-07-24 Published:1985-07-24

PDF (PC)

摘要： 新合成了双(均三甲苯基环辛四烯)钍夹心物和双(邻甲苯基环辛四烯)钍夹心物和双(联环辛四烯基)钍夹心物,进行了结构鉴定。改善了双(叔丁基环辛四烯)钍夹心物的制备。

Abstract: Three new substituted Thorocenes-1, 1'-dimesitylthorocenc, 1, 1'-di-o-toiyl-thorppene and 1, 1'-di-cyclooctatetraenylthorocene-were synthesized and characterized. There was improved the preparation of 1, 1' -di-t-butylthorocene and measured the UVabsorption spectrum of this thoroccnc.

TrendMD: