高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (7): 569.

• 研究论文 •    下一篇

乙酰丙酮-5,10,15,20-四-(对氯苯基)卟啉稀土配合物的制备和性质

刘国发   

  1. 吉林大学理论化学研究所
  • 收稿日期:1984-01-26 出版日期:1985-07-24 发布日期:1985-07-24

Preparation and Properties of Acetylacetonate 5,10,15, 20-Tetra-(p-Chlorophenyl) Porphyrin Rare Earth Complexes

Liu Guofa   

  1. Institute of Theoretical Chemistry, Jilin University, Changchun
  • Received:1984-01-26 Online:1985-07-24 Published:1985-07-24

摘要: 用丙酸做溶剂,吡咯与对氯笨甲醛反应制备5,10,15,20-四-(对氯苯基)卟啉(p-Cl)Tpp;后者与稀土乙酰丙酮配合物Ln(acac)3·3H2O在1,2,4-三氯苯中反应制得乙酰丙酮-5,10,15,20-四-(对氯苯基)卟啉稀土配合物Ln(p-Cl)Tppacac;并做了元素分析、UV、IR和PMR等性质的研究。

Abstract: Acetylacetonate-5,10,15,20-tetra-(p-chlorophenyl) porphyrin rare earth complexes Ln (p-Cl) Tppacac (Ln:Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb and Lu) have been synthesized by the direct reaction of (p-Cl) Tpp with Ln(acac)3·3H2Oin1,2,4-trichlorobenzene.Their properties were discussed simply.

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