高等学校化学学报

高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (6): 562.

• 研究简报 • 上一篇    下一篇

电子给体结构对丙烯腈光聚合的影响

曹维孝, 韩平, 贺霞, 冯新德   

  1. 北京大学化学系
  • 收稿日期:1983-12-27 出版日期:1985-06-24 发布日期:1985-06-24

The Structral Effect of Electron Donors on the Photo-Polymerization of Acrylonitrile

Cao Weixiao, Han Ping, He Xia, Feng Xinde   

  1. Department of Chemistry, Peking University, Beijing
  • Received:1983-12-27 Online:1985-06-24 Published:1985-06-24

PDF (PC)

被引次数

3

摘要： 电子受体与烯类单体间通过电荷转移机理的引发聚合已有很多研究,而电子给体如芳香叔胺、二苯硫醚等引发丙烯腈(AN)光聚合亦已证明都是通过电荷转移机理进行的。

Abstract: The photopolymerization of acrylonitrile (AN) using the triphenyl compounds of N, P, As, Sb, Bi elements (represented as (C6H5)3D) and the diphenyl compounds of O, Selements (represented as (C6H5)2D) as initiators and some relationship between the centre atom Dof the donor compounds and their situations in the periodic table were suggested.

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