二硫代乙酰丙酮和某些金属离子络合反应的研究

高等学校化学学报 ›› 1985, Vol. 6 ›› Issue (6): 521.

二硫代乙酰丙酮和某些金属离子络合反应的研究

黄建全¹, 黄金陵¹, 庄鸿辉², 林贤梯², 吴鼎铭², 商茂虞², 郑建基²

1. 福州大学;
2. 中国科学院福建物质结构研究所

收稿日期:1984-02-18 出版日期:1985-06-24 发布日期:1985-06-24

Researches on the Complex Reactions of Dithioacetylacetone with Some Metal Ions

Huang Jianquan¹, Huang Jinling¹, Zhuang Honghui², Lin Xianti², Wu Dingming², Shang Maoyu², Zheng Jianji²

1. Department of Chemistry, Fuzhou University, Fuzhou;
2. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou

Received:1984-02-18 Online:1985-06-24 Published:1985-06-24

摘要/Abstract

摘要： 报导CH₃COCH₂COCH₃/H-2S/C₂H₅OH-HCl体系和十六种金属离子以及Fe(CO)₅的反应,用X射线衍射法测定了九种反应产物的分子和晶体结构.本文结果总结出了该反应的规律性.研究表明,在该反应条件下,钼是唯一能够形成原子簇化合物的元素.

Abstract: This paper reports the research on the reactions of a variety of metal ions with dithioacetylacetone in a ethanol medium saturated with HCl The products of the reactions have been characterized by X-ray crystal structure analysis.The result shows that the complex types formed for different metal ions can be classified into three categories which are in coincidence with the division of metal ions according to their Z²/r as a function of (x_s + X_M/(X_s - X_M). In addition,it is found that among the ions used in the examination,the molybdenum is the only one element capable to form the cluster compound under such a specific reaction condition.

TrendMD:

黄建全, 黄金陵, 庄鸿辉, 林贤梯, 吴鼎铭, 商茂虞, 郑建基. 二硫代乙酰丙酮和某些金属离子络合反应的研究. 高等学校化学学报, 1985, 6(6): 521.

Huang Jianquan, Huang Jinling, Zhuang Honghui, Lin Xianti, Wu Dingming, Shang Maoyu, Zheng Jianji. Researches on the Complex Reactions of Dithioacetylacetone with Some Metal Ions. Chem. J. Chinese Universities, 1985, 6(6): 521.